What comes to mind when you think of alcohol? Probably alcoholic drinks like beer or wine. But in organic chemistry alcohols are an important and versatile family of compounds. In this episode of Crash Course Organic Chemistry, we’ll use alcohols as a starting point to get other types of compounds like ethers, epoxides, and more!
make your bed. (no, really.)
set your top 3 to-dos for the day.
do your top 3 to-dos for the day. (heh)
stretch.
unpack your bag when you get home.
prepare your things for the next day before sleeping.
skincare. (your basic cleanse and moisturize)
sweep the floor of your bedroom.
talk to your plants. (if you have plants)
update your financial report/expense tracker.
take a good photo.
meditate.
hug at least three people. (seriously.)
polish your school shoes.
mop your bedroom floor.
dare i say, laundry. (don’t put it off!)
exfoliate.
take a leisure walk.
review your past week and plan your next week accordingly. (a part of your routine may not be working–try something new)
make a piece of art. (a sketch, a collage, a quote in pretty lettering, a god-awful poem..)
sanitize your gadgets. (whip out the wet tissue and wipe away at your phone, your laptop, your mouse, your earphones–just don’t forget to IMMEDIATELY follow that up with a dry cloth to prevent fogging and short circuits)
watch a TED Talk.
make a new playlist.
wash your bag.
wash your shoes.
change the sheets of your bed and your pillows.
clip your nails. (honestly)
wax/shave. (if you want. i just really like how fresh my skin feels after i torture it with razors and wax strips)
wipe your shelves/the tops of your furniture clean. (try to avoid dusting. it just scatters the dirt everywhere. use a damp cloth instead)
see if there’s anything in your storage that you don’t need/want anymore and give stuff away or sell them.
review your month and plan the next one accordingly. (just like your weeks. remember to refer to your Life Goal/Year’s Goals page)
finish reading at least one book. (and review it!)
discover new songs.
- 🍂
i just learned from animal crossing that pondskaters stay on top of the water by secreting an oil from their feet
that seems kinda obvious in hindsight. i always figured they were just, like, light enough to not break surface tension
My friend sent this to her Professor today
Today is #InternationalMakeUpDay! Here’s a graphic looking at the various components of nail polish 💅 https://ift.tt/32fnwAh https://ift.tt/3jWclTk
Universities are like "we can't accept everyone based on accepted grades because we gave too many offers out." They give out too many offers because they're horrified at the thought that they might end up with too many empty places on courses, so they oversubscribe so they can get those sweet sweet tuition fees.
Just in case anyone thought here was a thing that Tony Blair had no hand in, for once.
Follow @productive-tips for more tips and content like this posted daily! Handpicked and curated with love :)
This is the first in my short series of the three main types of bond - ionic, metallic and covalent. In this, you’ll learn about the properties of the compounds, which atoms they’re found between and how the bonds are formed. Enjoy!
When electrons are transferred from a metal to a non-metal, an ionic compound is formed. Metals usually lose electrons and non-metals usually gain them to get to a noble gas configuration. Transition metals do not always achieve this.
Charged particles that have either lost or gained electrons are called ions and are no longer neutral - metal atoms lose electrons to become positive ions (cations) whereas non-metals gain electrons to become negative ions (anions).
The formation of these ions is usually shown using electron configurations. Make sure you know that the transfer of electrons is not the bond but how the ions are formed.
An ionic bond is the electrostatic attraction between oppositely charged ions.
You need to know how to explain how atoms react with other atoms and for this the electron configurations are needed. You can use dot and cross diagrams for this.
Ionic solids hold ions in 3D structures called ionic lattices. A lattice is a repeating 3D pattern in a crystalline solid. For example, NaCl has a 6:6 arrangement - each Na+ ion is surrounded by 6 Cl- and vice versa.
Ionic solids have many strong electrostatic attractions between their ions. The crystalline shape can be decrepitated (cracked) on heating. Ionic Lattices have high melting and boiling points since they need more energy to break because atoms are held together by lots of strong electrostatic attractions between positive and negative ions. The boiling point of an ionic compound depends on the size of the atomic radius and the charge of the ion. The smaller the ion and the higher the charge, the stronger attraction.
Look at this diagram. It shows how atomic radius decreases across a period regularly. This is not the case with the ions. Positive ions are usually smaller than the atoms they came from because metal atoms lose electrons meaning the nuclear charge increases which draws the electrons closer to the nucleus. For negative ions, they become larger because repulsion between electrons moves them further away - nuclear charge also decreases as more electrons to the same number of protons.
Ionic substances can conduct electricity through the movement of charged particles when molten or dissolved (aqueous). This is because when they are like this, electrons are free to move and carry a charge. Ionic solids cannot conduct electricity.
Ionic compounds are usually soluble in water. This is because the polar water molecules cluster around ions which have broken off the lattice and so separate them from each other. Some substances like aluminium oxide have too strong electrostatic attractions so water cannot break up the lattice - it is insoluble in water.
Molecular ions such as sulfate, nitrate, ammonium or carbonate can exist within ionic compounds. These compounds may have covalent bonds within the ions but overall they are ionic and exhibit thee properties described above.
SUMMARY
When electrons are transferred from a metal to a non-metal, an ionic compound is formed.
Charged particles that have either lost or gained electrons are called ions and are no longer neutral - metal atoms lose electrons to become positive ions (cations) whereas non-metals gain electrons to become negative ions (anions).
The formation of these ions is usually shown using electron configurations. The transfer of electrons is not the bond but how the ions are formed.
An ionic bond is the electrostatic attraction between oppositely charged ions.
Ionic solids hold ions in 3D structures called ionic lattices. A lattice is a repeating 3D pattern in a crystalline solid.
Ionic solids have many strong electrostatic attractions between their ions. The crystalline shape can be decrepitated (cracked) on heating.
Ionic Lattices have high melting and boiling points since they need more energy to break because atoms are held together by lots of strong electrostatic attractions between positive and negative ions.
The boiling point of an ionic compound depends on the size of the atomic radius and the charge of the ion. The smaller the ion and the higher the charge, the stronger attraction.
Positive ions are usually smaller than the atoms they came from because metal atoms lose electrons meaning the nuclear charge increases which draws the electrons closer to the nucleus. Negative ions become larger because repulsion between electrons moves them further away - nuclear charge also decreases as more electrons to the same number of protons.
Ionic substances can conduct electricity through the movement of charged particles when molten or dissolved (aqueous). This is because when they are like this, electrons are free to move and carry a charge. Ionic solids cannot conduct electricity.
Ionic compounds are usually soluble in water because the polar water molecules cluster around ions which have broken off the lattice and so separate them from each other.
Some substances like aluminium oxide have too strong electrostatic attractions so water cannot break up the lattice - it is insoluble in water.
Molecular ions such as sulfate, nitrate, ammonium or carbonate can exist within ionic compounds. These compounds may have covalent bonds within the ions but overall they are ionic and exhibit thee properties described above.
A short one to finish off my first ever mini-series on bonding – ionic, covalent and finally metallic. There are metallic and metallic compounds and elements but for the A Level exam, we must look at the bonding within metals themselves. Don’t worry – I saved the easiest to last!
Metals are most usually solid so have particles packed close together. These are in layers which mean that the outer electrons can move between them rather than being bound to particular atoms. These are referred to as delocalised electrons because of this.
It’s pretty common knowledge that metals are good conductors of heat and electricity and it’s these delocalised electrons that give them this property.
Metals are therefore without their electrons so become positive ions. The metallic bond is actually the attraction between delocalised electrons and positive metal ions in the lattice. And that’s pretty much metallic bonding, you just need to know the properties of metals which are touched upon at lower levels of education.
These are the properties of metals:
1. High melting points
Metals have large regular structures with strong forces between the oppositely charged positive ions and negative electrons, meaning these must be overcome to melt the metal – this requires a large amount of heat energy. Transition metals tend to have higher melting points than the main group metals because they have large numbers of d-shell electrons which can become delocalised creating a stronger metallic bond. Melting points across a period increase because they can have progressively more delocalised electrons: Na+, Mg 2+ and Al 3+ for example.
2. Heat conductivity
Heat is conducted if particles can move and knock against each other to pass it on. Delocalised electrons allow this to happen. Silver is a particularly good conductor of heat.
3. Electrical conductivity
Delocalised electrons can carry charge and move, the two requirements of electrical conductivity. Current can flow because of these delocalised electrons.
4. Ductile and malleable
Metals can be stretched and hammered into shape, making them ideal for things such as wires. Layered lattices mean that layers can slide over each other without disrupting the bonding – it is all still held together by the delocalised electrons and their strong attraction to the positive metal ions.
5. High densities
Being a solid, metal ions are packed closely together so they have a high density, which makes them ideal for musical instrument strings. These can withstand the frequency of vibration whilst also being thinner.
SUMMARY
Metals are solid so have particles packed close together. These are in layers which mean that the outer electrons can move between them rather than being bound to particular atoms. These are referred to as delocalised electrons because of this.
Metals are therefore without their electrons so become positive ions. The metallic bond is actually the attraction between delocalised electrons and positive metal ions in the lattice.
Metals have high melting points.
Metals have large regular structures with strong forces between the oppositely charged positive ions and negative electrons, meaning these must be overcome to melt the metal – this requires a large amount of heat energy. Transition metals tend to have higher melting points than the main group metals because they have large numbers of d-shell electrons which can become delocalised creating a stronger metallic bond.
Metals conduct heat.
Heat is conducted if particles can move and knock against each other to pass it on. Delocalised electrons allow this to happen.
Metals have good electrical conductivity
Delocalised electrons can carry charge and move, the two requirements of electrical conductivity. Current can flow because of these delocalised electrons.
Metals are ductile and malleable.
Metals can be stretched and hammered into shape, making them ideal for things such as wires. Layered lattices mean that layers can slide over each other without disrupting the bonding – it is all still held together by the delocalised electrons and their strong attraction to the positive metal ions.
Being a solid, metal ions are packed closely together so they have a high density.
Happy studying!
So you want to be an organic chemist? Well, learning about hydrocarbons such as alkanes is a good place to start…
Alkanes are a homologous series of hydrocarbons, meaning that each of the series differs by -CH2 and that the compounds contain carbon and hydrogen atoms only. Carbon atoms in alkanes have four bonds which is the maximum a carbon atom can have - this is why the molecule is described to be saturated. Saturated hydrocarbons have only single bonds between the carbon atoms.
The general formula of an alkane is CnH2n+2 where n is the number of carbons. For example, if n = 3, the hydrocarbon formula would be C3H8 or propane. Naming alkanes comes from the number of carbons in the chain structure.
Here are the first three alkanes. Each one differs by -CH2.
Shorter chain alkanes are gases at room temperature, medium ones are liquids and the longer chain alkanes are waxy solids.
Alkanes have these physical properties:
1. They are non-polar due to the tiny difference in electronegativity between the carbon and hydrogen atoms.
2. Only Van der Waals intermolecular forces exist between alkane molecules. The strength of these increase as relative molecular mass increases therefore so does the melting/boiling point.
3. Branched chain alkanes have lower melting and boiling points than straight chain isomers with the same number of carbons. Since atoms are further apart due to a smaller surface area in contact with each other, the strength of the VDWs is decreased.
4. Alkanes are insoluble in water but can dissolve in non-polar liquids like hexane and cyclopentane. Mixtures are separated by fractional distillation or a separating funnel.
The fractional distillation of crude oil, cracking and the combustion equations of the alkanes will be in the next post.
SUMMARY
Alkanes are a homologous series of hydrocarbons. Carbon atoms in alkanes have four bonds which is the maximum a carbon atom can have - this is why the molecule is described to be saturated. Saturated hydrocarbons have only single bonds between the carbon atoms.
The general formula of an alkane is CnH2n+2 where n is the number of carbons.
Shorter chain alkanes are gases at room temperature, medium ones are liquids and the longer chain alkanes are waxy solids.
They are non-polar.
Only Van der Waals intermolecular forces exist between alkane molecules. The strength of these increase as relative molecular mass increases therefore so does the melting/boiling point.
Branched chain alkanes have lower melting and boiling points than straight chain isomers with the same number of carbons.
Alkanes are insoluble in water but can dissolve in non-polar liquids like hexane. Mixtures are separated by fractional distillation or a separating funnel.